CAS
NO. |
7637-07-2
|
|
EINECS
NO. |
231-569-5
|
FORMULA |
BF3
|
MOL
WT. |
99.83
|
H.S.
CODE |
2942.00 |
TOXICITY
|
|
SYNONYMS |
Trifluoro Borane; Boron fluoride; Fluorure de bore (French); |
SMILES
|
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES (50%
IN METHANOL)
|
PHYSICAL
STATE |
clear
to pale
yellow liquid |
MELTING
POINT |
-20
C |
BOILING
POINT |
59 C
at 4.00 hPa |
SPECIFIC
GRAVITY |
1.21
- 1.23
|
SOLUBILITY
IN WATER |
Hydrolysis |
pH |
Acidic |
VAPOR
DENSITY |
|
AUTOIGNITION
|
420
C
|
NFPA
RATINGS |
Health:
3; Flammability: 4; Reactivity: 0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
68
C
|
STABILITY |
exposure to the
moisture of air fumes
|
GENERAL
DESCRIPTION AND APPLICATIONS
|
Borane
(boron hydride) is any binary compounds of boron and
hydrogen, which can be made from magnesium boride (MgB2)
with the action of acid or can be prepared by the breaking
apart of complex molecules into simpler products on
heating in the presence of hydrogen. Boranes form interesting
structures which cannot be described by the conventional
two-electron covalent bond model. There are fewer electrons
forming the chemical bonds than required in normal electron-pair
bonds. An electron pair bonds both borons and the bridging
hydrogen atom to create three atoms bond. The simplest
is diborane (B2H6), highly reactive
gas, used as fuels for air breathing engines and rockets
and used in the synthesis of other organic boron compounds
and metal borohydrides. Boranes are all reactive and
oxidize readily in air. There is a wide range of boranes
with shapes ranging from delicate spiders' webs to untidy
birds' nests. There is also a wide range of borane derivatives
containing other atoms, such as carbon and phosphorus.
Carborane is any of a class of stable compounds containing
carbon, hydrogen, and boron having general formula C2BnHn+2.
Boranes are used as polymerization initiators (especially
Trialkylboranes) for many monomers and chemo- or stereo-selective
reductants. They convert aldehydes (chemoselective),
ketones (stereoselective) to the corresponding alcohols
in the manufacture of pharmaceuticals and other fine
chemicals. They are used in the reductive alkylation
of amines, novel metals and oximes. Boron Trifluoride
is a very powerful Lewis acid which forms numerous
chemical
compounds. It is used as an agent for the surface treatment of steel and glass. It is a
starting material for the production of active agents in pharmaceuticals and for
the production of boranes and borates including tri (tetra) phenylborates.
|
SALES
SPECIFICATION |
APPEARANCE
|
clear to pale
yellow liquid |
BF3
|
50.0%
min
|
METHANOL
|
Balance
|
TRANSPORTATION |
PACKING |
240kgs
in drum |
HAZARD
CLASS |
3
(Packing Group: II ) |
UN
NO. |
2924 |
OTHER
INFORMATION |
Hazard Symbols: T F, Risk Phrases: 11-23/25-34,
Safety Phrases: 2-7-9-16-24/25-25-26-28-33-36/37/39-38-44-45 |